The Infona portal uses cookies, i.e. strings of text saved by a browser on the user's device. The portal can access those files and use them to remember the user's data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser.
Readily accessible nitrilium triflates are convenient imine building blocks for the expedient synthesis of a novel class of 1,3‐P,N ligands as demonstrated for the reaction with primary phosphanes. This procedure allows variation of all substituents. X‐ray crystal structures are reported for nitrilium ions, phosphaamidines, and three phosphaamidinate complexes. The lithium phosphaamidinate is N coordinated...
Geladen! Die Kombination von MeBABAR‐Phos und Methyltriflat ergibt ein aminostabilisiertes Phosphiranyliumion (siehe Bild; C grau, N blau, P orange), das verschiedene nucleophile Additionsreaktionen eingeht. Dabei bilden sich P‐substituierte Phosphirane sowie ein Phosphiranyliumkation, das durch ein N‐heterocyclisches Carben stabilisiert wird.
Set the date range to filter the displayed results. You can set a starting date, ending date or both. You can enter the dates manually or choose them from the calendar.