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The impact of branching architecture of one continuous uncrosslinked phase on properties of classic shape memory semi‐interpenetrating polymer networks (semi‐IPNs) was explored. Crosslinked poly (methyl methacrylate) (PMMA)/star‐shaped polyethylene glycol (PEG) (PMMA/SPEG) semi‐IPNs and PMMA/linear PEG (PMMA/LPEG) semi‐IPNs were synthesized with the same PEG content. Mechanical properties, phase structure,...
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