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One pot catalytic H2 auto transfer amination of glycerol to alkyl amines is reported for the first time using supported Ru catalysts. It is found that, compared to other noble metal catalysts, Ru/C catalyst exhibits a remarkable activity and selectivity for conversion of glycerol and sorbitol to alkyl amines in the aqueous phase. Detailed experimental studies show that catalyst support, reaction temperature...
Unsupported Ni–Mo sulfide catalysts were prepared by thermal decomposition of tetramethylammonium thiomolybdostate and nickel nitrate, which were characterized by Fourier transform infrared spectroscopy, ultraviolet–visible spectroscopy, thermogravimetric and differential thermal analysis, X-ray diffraction, N 2 physorption, elemental mapping and transmission electron microscopy. Hydrodesulfurization...
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