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B4C‐TiB2 ceramics (TiB2 ranging 5~70 vol%) with Mo‐Co‐WC as the sintering additive were prepared by spark plasma sintering. In comparison with B4C‐TiB2 without additive, the enhanced densification was evident in the sintered specimen with Mo‐Co‐WC additive. Core‐rim structured grain was observed around TiB2 grains. The interface of the rim between TiB2 and B4C phases demonstrated different feature:...
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