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Complexes [Rh(nbd)(acac)], [Rh(cod)(acac)] and [Rh(cot)(acac)] (nbd=norborna-2,5-diene, cod=cycloocta-1,5-diene, cot=cyclooctatetraene) were investigated as catalysts of polymerization of monosubstituted acetylenes into stereoregular cis-transoid poly(monosubstituted acetylene)s. All complexes (without cocatalyst) are highly active in phenylacetylene (PhA) polymerization in both coordinating (THF)...
Nanostructured epoxy networks, based on DGEBA and poly(oxypropylene)diamine (Jeffamine D), containing nano-sized inorganic blocks, polyhedral oligomeric silsesquioxanes (POSS), were investigated. The POSS were incorporated in the network as crosslinks or as pendant units by using octa- or monoepoxy-POSS monomers, respectively, as well as diepoxides with pendant POSS. The authors focused on investigating...
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