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The ferrocene tertiary amines of general formula [(η5C5H5)Fe(η5C5H4)CH2N(CH3)CH2C(R)CHC6H5, RH (3a) and RCH3 (3b)] were conveniently prepared from the corresponding ferrocenylimines [(η5C5H5)Fe(η5C5H4)CH2NCHC(R)CHC6H5, RH (1a) and RCH3 (1b)] in two steps. Metalation of 3a, 3b with Li2PdCl4 and CH3COONa, followed by treatment with PPh3, gave the ortho palladium (II) complexes Pd{[(η5C5H5)Fe(η5C5H3)CH...
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