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The thermal properties and some physical characteristics of the metaphosphate glassy system xMnO–(50−x)ZnO–50P2O5 were studied. Homogeneous glasses were obtained in the whole concentration range between Zn(PO3)2 and Mn(PO3)2. The metaphosphate structure of the glasses was confirmed by Raman spectroscopy. The manganese was found to have a high-spin d5-configuration in the glassy network, i.e., Mn(II),...
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