The Infona portal uses cookies, i.e. strings of text saved by a browser on the user's device. The portal can access those files and use them to remember the user's data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser.
It is often said that pnictogen‐bonding catalysis, and σ‐hole catalysis in general, would not work in aqueous systems because the solvent would interfere as an overcompetitive pnictogen‐bond acceptor. In this study, we show that the transfer of pnictogen‐bonding catalysis from hydrophobic solvents to aqueous systems is possible by replacing only hydrophobic with hydrophilic substrates, without changing...
A hyperresponsive tool to assess supramolecular catalysis, the cyclization of di‐epoxides into cyclic ethers is used to elucidate the difference between pnictogen‐bonding and Lewis acid catalysis systematically. For all stereoisomers, most tested catalysts follow the Baldwin rules. Brønsted acid and anion–π catalysis afford almost only Baldwin products. Lewis acids such as SbCl3, BF3 and BiCl3 give...
Set the date range to filter the displayed results. You can set a starting date, ending date or both. You can enter the dates manually or choose them from the calendar.