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The effects of the morphology of anatase TiO2 substrates on the adsorption nature of Ru‐bipyridyl complexes with carboxylate groups as anchoring moieties have been investigated with infrared absorption spectroscopy and electron microscopy. The investigated dyes were the recently synthesized [Ru(dcbpyH2)2(bpy‐TPA2)](PF6)2, Ru‐TPA2, and the well‐known (Bu4N)2[Ru(dcbpyH)2(NCS)2], N719, complexes. As...
In situ ATR–FTIR spectroscopy has been extended to the study of CO and pyridine adsorptions at crystalline and amorphous Ni–P alloy film electrodes, with an emphasis on the alloying effect of P on their adsorption configurations on Ni sites. The Ni–P films were prepared with initial seeding of a catalytic Pd layer on Si, followed by chemical deposition. Transition from bridge-bonded CO (CO B ...
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