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Fe16N2 nanoparticles with a diameter of 20nm were produced with ammonia nitrification of metallic Fe particles reduced from Fe oxide nanoparticles. The samples were gradually exposed to air and the outer side of 2nm was oxidized. The particles exhibit coercivity as high as 3350Oe. By using this core–shell type round shaped particles, uniaxial magnetic anisotropy Ku can be determined to be 4.4×106erg/cm3...
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