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Nicotinamide adenine dinucleotide (NAD) is the redox cofactor of many enzymes, including the vast aldehyde dehydrogenase (ALDH) superfamily. Although the function of NAD(H) in hydride transfer is established, its influence on protein structure is less understood. Herein, we show that NAD+‐binding promotes assembly of the ALDH7A1 tetramer. Multiangle light scattering, small‐angle X‐ray scattering,...
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