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A 22‐membered cyclic alkene C1 incorporating an exotopic 1,10‐phenanthroline nucleus in the ring skeleton has been synthesized and subjected to ring‐opening metathesis polymerization (ROMP) in dilute dichloromethane solution at varying monomer concentrations (cmon). The resultant libraries of macrocyclic oligomers were used as ligands for the generation of main‐chain metal–ligand oligomeric/polymeric...
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