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Das erste quasi‐binäre Acetonitriltriid Sr3[C2N]2 wurde durch Reaktion von Sr‐Metall, Graphit und elementarem N2, erzeugt durch Zersetzung von Sr(N3)2, in einer verschlossenen Ni‐Ampulle mithilfe einer Alkalimetallschmelze in Form von nahezu farblosen Kristallen erhalten. Die Kristallstruktur der Verbindung wurde mittels Einkristall‐Röntgenbeugung bestimmt, die Identität des [C2N]3−‐Anions durch Raman‐Spektroskopie...
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