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The single-molecule conductance of 1,4-dicyanobenzene (DCB), 1,4-benzenediamine (BDA) and 4,4'-biphenyldicarbonitrile (BPDC) with Ag and/or Cu electrodes is measured by electrochemical jump-to-contact STM-break junction. All single-molecule junctions present three sets of conductance values revealing different contact geometries. We observe that the single-molecule conductance of Ag-BDA-Ag junction...
We measured the single-molecule conductance of alkanedicarboxylic acid (HOOC−(CH 2 ) n −COOH, n=1−5) with Pd nanoclusters by electrochemical jump-to-contact STM-break junction. They gave out decay constant β N of 0.652 per (−CH 2 ) unit and contact conductance of 97 nS. The single-molecule conductance of carboxylic acid binding to bulk metal electrode was also studied,...
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