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Asymmetric hydrogenation of 1,1 -disubstituted olefins which have no heteroatom functionalities to allow additional interactions with catalyst centers, have been investigated by use of Ru(II) and Rh(I) complexes of BINAP as catalysts. Enantioselectivities and the sense of asymmetric induction are highly dependent on the structure of substrates and the nature of catalysts. Hydrogenation of 1-methyleneindan...
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