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A novel selenization process is used to prepare Cu2Zn(Sn,Ge)(S,Se)4 (CZTGSSe) thin films. During this selenization process, Ge is introduced into the solution deposited precursors from a GeSe2 source and assists the formation and crystallization of CZTGSSe. The composition, morphology and phases for the selenized films are investigated and solar cells are prepared. The results suggest Ge is incorporated...
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