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Triflate (–OTf) and triflimide (–NTf2) represent two most widely used weakly coordinating counteranions in transition metal catalysis, yet their high price hinders large‐scale application. Herein, we report the preparation, characterization, and catalytic applications of silver(I), gold(I), and copper(II) (bisfluorosulfonyl)imide (–FSI) complexes, showing –FSI as a low cost alternative of –OTf and...
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