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A newly developed technology, rotationally accelerated shot peening (RASP), was used to produce the nanocrystals on the surface of 316LN stainless steel. The effect of surface nanocrystallization on the oxide film properties of the steel in a high temperature and high‐pressure aqueous environment was studied. It was found that the outer layer of the oxide film consisted of NiFe2O4 with a loose spinel...