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A hetero-metallic cluster {Cp ∗ Ir[S 2 C 2 (B 10 H 10 )]} 2 Mo(CO) 2 (2) has been synthesized and structurally characterized, and their third-order nonlinear optical (NLO) properties have been investigated by Z-scan technique. The results indicate that 2 exhibit good NLO absorption and self-focusing effects. The hyperpolarizability γ value is...
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