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The activation of SF6, a potent greenhouse gas, under metal‐free and visible light conditions is reported. Herein, mechanistic investigations including EPR spectroscopy, NMR studies and cyclic voltammetry allowed the rational design of a new fluorinating reagent which was synthesized from the 2‐electron activation of SF6 with commercially available TDAE. This new SF5‐based reagent was efficiently...
The activation of SF6, a potent greenhouse gas, under metal‐free and visible light conditions is reported. Herein, mechanistic investigations including EPR spectroscopy, NMR studies and cyclic voltammetry allowed the rational design of a new fluorinating reagent which was synthesized from the 2‐electron activation of SF6 with commercially available TDAE. This new SF5‐based reagent was efficiently...
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