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This review describes four recent examples of how photoinduced energy-transfer in dinuclear complexes can be manipulated or controlled according to the nature of the bridging pathway between the metal-polypyridyl luminophores. In the first examples, the interacting fragments [polypyridyl complexes of Ru(II), Os(II) or Re(I)] are covalently linked by the bridging ligand 2,2′:3′,2′′:6′′,2′′′-quaterpyridine...
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