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An in-depth study of the first steps of electron beam assisted growth of Mo from molybdenum hexacarbonyl on Cu(111) has been carried out exploiting the complementarity of X-ray photoemission and X-ray absorption spectroscopies. Frank van der Merwe (2D) growth mode has been observed for the completion of the two first monolayers of adsorbed molecules through a simple physisorption process. Irradiation...
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