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Two series of multi-cascade scaffolds bearing a boradiazaindacene (yellow dye) or a boradibenzopyrromethene (green dye) as the final energy acceptor have been synthesized. Each scaffold contains one, two or three alkynylaryl energy donors (such as pyrene D 1 , perylene D 2 , and fluorene D 3 ) linked to the boron center. Palladium-catalyzed cross-coupling of dihalogenated Bodipy...
The synthesis of novel ruthenium(II) bipyridine or terpyridine complexes bearing an increasing number of pyrene or toluyl moieties is described. The ruthenium complexes are constructed in a first step with ligands bearing the required bromine functions, followed in a second step by stepwise grafting of 1-ethynylpyrene or 4-ethynyltoluene promoted by Pd(0). A complex bearing a protected triethylsilylacetylene...
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