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In order to create photoactive catalysts for hydrogen production, a novel trimetallic Re–Fe 2 S 2 complex 4 was synthesized by the coordination of the free –PPh 2 group of the ligand of the rhenium photosensitizer 6 to an azadithiolate (ADT)-bridged diiron complex 8 with the assistance of the decarbonylation reagent Me 3 NO. Complex 4 was characterized by 1 ...
The preparation and characterization of two novel amino-incorporated sulfur-bridged dinuclear iron (I) complexes of the type [NR(μ-SCH 2 ) 2 ]Fe 2 (CO) 6 , one being amino protected [N(CH 2 CH 2 NHTs)(μ-SCH 2 ) 2 ]Fe 2 (CO) 6 (8) and the other [(μ- SCH 2 ) 2 Fe 2 (CO) 6 NCH 2 CH...
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