Search results for: Weiwei Zhu
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Part 2. Tertbutyl's electronic and steric effects
Journal of Molecular Catalysis. A, Chemical > 2005 > 230 > 1-2 > 135-141
Six Sm(III) phenolates were firstly synthesized with un-substituted phenol (P), 2-tertbutylphenol (2B), 4-tertbutylphenol (4B), 4-methylphenol (4M), 2-tertbutyl-4-methylphenol (2B4M) and 2,6-ditertbutyl-4-methylphenol (26B4M) separately. All the phenolates were used as single component catalyst for the ring-opening polymerization (ROP) of ɛ-caprolactone (CL). The experimental results showed that,...
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