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Perylenediimide (PDI)-based small molecules have significantly contributed to the development of non-fullerene acceptors, whereas the development of PDI-based polymer acceptors is relatively lagging behind. In this study, we designed and synthesized two PDI-based n-type polymers named as PF-PDI and PBDT-PDI, in which PDI was used as electron-deficient unit and fluorene (F) or benzodithiophene (BDT)...
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