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The linear dynamic rheology for a series of filled polymer melts is investigated to take account for the respective contributions of the bulky polymer phase away from the filler inclusions and the “filler phase” composed of filler particles coated with polymer layer. Time-concentration superposition principles are introduced to the linear viscoelasticities of both the bulky polymer phase and the “filler...
The linear dynamic rheology of polymer melts filled with nano-sized fillers is investigated in relation to a proposed two phase model. A common principle is disclosed for nanofilled polymers exhibiting either fluid- or solid-like behaviors with increasing filler volume fraction. The bulky polymer phase far away from the filler inclusions in the nanocomposites behaves the same as in the unfilled case...
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