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In this paper, a pectin polysaccharide AP2‐c with molecular weight 6.69 × 105 Da was obtained from the lignified okra. The monosaccharide composition analysis indicated that AP2‐c consisted of galactose, rhamnose and galacturonic acid in a molar ratio of 2.3: 1.5: 1.5. The structural characterization indicated that the main chain of AP2‐c was composed of →2)‐α‐L‐Rhap‐(1→ and →4)‐α‐D‐GalAp‐(1→. →2)‐α‐L‐Rhap‐(1→...