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Boron Compounds. The synthesis of 2,3‐dihydro‐2,3‐diiminoboroles through regioselective double insertion of isocyanide into benzoborirenes is reported by Max C. Holthausen, Qing Ye et al. in their Communcation (e202312608).
Die Reaktion von Benzoborirenen mit einem Äquivalent Isocyanid führt zu benzolkondensierten Boreten mit einer Iminfunktion, während die Reaktion mit zwei Äquivalenten Isocyanid 2,3‐Dihydro‐2,3‐diiminoborole mit perfekter Regioselektivität ergibt. Die Isocyanid‐Doppelinsertionsprodukte stellen einen neuen Typ von 1,2‐Diiminen mit einem Benzoborol‐Rückgrat dar. Die Reduktionschemie des Benzoborol‐basierenden...
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