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Bottom‐up multicomponent molecular self‐assembly is an efficient approach to fabricate and manipulate chiral nanostructures and their chiroptical activities such as the Cotton effect and circular polarized luminescence (CPL). However, the integrated coassembly suffers from spontaneous and inherent systematic pathway complexity with low yield and poor fidelity. Consequently, a rational design of chiral...
Construction of integrated self‐assembly with ordered structures from two or more organic building blocks is currently a challenge, since it suffers from intrinsic systematic complexity and diverse competitive pathways. Here, it is reported that aromatic amino acid building units can be incorporated into two‐ or three‐component coassembly driven primarily by hydrogen bonding interactions without the...
Controlling the structural parameters in coassembly is crucial for the fabrication of multicomponent functional materials. Here a proof‐of‐concept study is presented to reveal the α‐substituent effect of aromatic amino acids on their selective coassembly with bipyridine binders. With the assistance of X‐ray scattering technique, it is found that individual packing in the solid state as well as bulky...
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