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We report a new synthesis method of fibrous carbon material with pores sizes that are precisely controlled at the Ångstrom level, by carbonization of two dimensional (2D) porous sheets of pillar[6]arenes. The 2D porous sheets were prepared by 2D supramolecular polymerization induced by oxidation of hydroquinone units of pillar[6]arenes. Owing to the hexagonal structure of pillar[6]arene, the assembly...
Das Einstellen der Porengröße im Ångstrom‐Bereich ist sehr schwierig und erfordert anorganische Template, die wieder entfernt werden müssen. In der Zuschrift auf S. 6566 ff. präsentieren T. Ogoshi et al. eine neue Methode für die Synthese poröser Kohlenstofffasern ohne anorganische Template. Das Karbonisieren der faserförmigen porösen 2D‐Schichten, die aus hexagonalen Pillar[6]arenen entstehen, liefert...
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