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The coupling of HSiEt3 and related silanes to β‐diiminate ligands is achieved through a series of SiH, CH, and SiC bond‐breaking and bond‐forming reactions. Complex 1 (see scheme) loses an Et(Si) group as ethane and couples the remaining SiEt2H fragment to a benzylic methyl group of the ligand skeleton. According to DFT calculations, the reaction involves silylene intermediates.
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