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Supramolekulare “Oktopus“‐Paare bilden sich, wenn ein positiv quadrupolares cyclisches AgI‐Triazolat‐Trimer mit fluorierten Seitenketten ein negativ quadrupolares freies Porphyrin oder PtII‐Porphyrin mit kürzeren Alkylseitenketten elektrostatisch anzieht. In ihrer Zuschrift auf S. 4924 ff. beschreiben C. Yang, M. A. Omary et al., dass in diesem System die Phosphoreszenz des Metalloporphyrins unter...
The trinuclear triangle‐shaped system [tris{3,5‐bis(heptafluoropropyl)‐1,2,4‐triazolatosilver(I)}] (1) and the multi‐armed square‐shaped metalloporphyrin PtOEP or the free porphyrin base H2OEP serve as excellent octopus hosts (OEP=2,3,7,8,12,13,17,18‐octaethyl‐21H,23H‐porphine). Coupling of the fluorous/organic molecular octopi 1 and H2OEP or PtOEP by strong quadrupole–quadrupole and metal–π interactions...
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