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The effects of doped low‐valence cations on the properties of the SnP2O7 proton conductor at ambient temperature are investigated from changes in solid‐state NMR spectra and nuclear magnetic relaxation times. Although the T1H values increased with decreasing acidity as a result of cation exchange, the 1H chemical shifts moved to lower field in Al‐ and In‐doped materials compared with undoped ones...
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