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Palladium-catalyzed C–C bond cleavage via β-carbon elimination occurs in various cyclic and acyclic systems. Thus, the reaction can be utilized as one of fundamental and effective tools in organic synthesis. The recent progress in this field is summarized herein.
Aromatic compounds having oxygen-containing substituents such as phenols, phenyl ketones, benzyl alcohols, and benzoic acids undergo regioselective arylation and vinylation via C–H bond cleavage in the presence of transition-metal catalysts. The latter two substrates are also arylated and vinylated via C–C bond cleavage accompanied by liberation of ketones and CO2, respectively. Coordination of their...
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