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Crystals of a lithiocuprate prepared from copper(I) chloride and lithium 2,2,6,6-tetramethylpiperidide (2equiv) were isolated and analyzed by X-ray diffraction as (TMP) 2 Cu(Cl)Li 2 ·THF. The observation of this species is consistent with its having a role in deprotocupration–aroylation. Phenyl pyridyl ketones, phenyl quinolyl ketones, and phenyl thienyl ketones were prepared in tetrahydrofuran...
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