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A few metal–organic frameworks (MOFs), which typically use strong acids as proton sources, display superprotonic conductivity (≈10−1 S cm−1); however, they are rare due to the instability of MOFs in highly acidic conditions. For the first time, we report superprotonic conductivity using a moderately acidic guest, zwitterionic sulfamic acid (HSA), which is encapsulated in MOF‐808 and MIL‐101. HSA acts...
Superprotonic conductivity , utilizing MOFs embedded with a moderately acidic guest—zwitterionic sulfamic acid (HSA)—was demonstrated by Myoung Soo Lah et al. in their Research Article (e202302376). HSA not only acted as a proton source, but also as a proton‐conducting medium. The MOFs, which had been filled with high quantities of HSA using a sustained concentration gradient method, exhibited impressive...
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