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2,18‐Bis(diphenylphosphino)porphyrins undergo peripheral cyclometalation with group 10 transition‐metal salts to afford the corresponding porphyrin‐based PCP pincer complexes. The porphyrinic plane and the PCP‐pincer unit are apparently coplanar, with small strain. The catalytic activities of the porphyrin‐based pincer complexes at the periphery were investigated in the allylation of benzaldehyde...
N ausgerenkt: Die Metallierung von [32]Heptaphyrinen(1.1.1.1.1.1.1) mit PdII führt zu PdII‐Komplexen mit N‐invertiertem Porphyringerüst (NCP; siehe Schema). Diese Umlagerung wurde auch für einen Monozink(II)‐Heptaphyrin‐Komplex mit Achter‐Konformation beobachtet. Auf dieser Grundlage sind NCPs als Mitglieder der Familie expandierter Porphyrine einzustufen.
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