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Polyethers are an important class of polymers that find numerous applications. Ring‐opening polymerization of various 1,2‐disubstituted epoxides initiating a commercial, and well‐defined CoIII‐Salen complex is investigated in this paper. Remarkable reactivity (0.01% CoIII loadings, TOF up to 19200 h−1) is discovered in this transformation. High molecular weight polymers (up to 80 kg mol−1) are produced...
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