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In this paper, we prepared Cu2Zn(Sn,Ge)(S,Se)4 (CZTGSSe) films based on a single-target sputtering method. This method involves the sputtering of precursor film from a compound target and a following selenization process with Se and GeSe2. The properties of the CZTGSSe film was compared with the CZTSSe film which was prepared using the same process but without using GeSe2 during the selenization....
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