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Halogenated buckybowls or bowl‐shaped polycyclic aromatic hydrocarbons (BS‐PAHs) are key building blocks for the “bottom‐up” synthesis of various carbon‐based nanomaterials with outstanding potential in different fields of technology. The current state of the art provides quite a limited number of synthetic pathways to BS‐PAHs; moreover, none of these approaches show high selectivity and tolerance...
Erstmals ist es gelungen, einen rationalen Syntheseplan – die “Funktionalisierung von para‐Nitroanilin” (FpNA) – zur Herstellung substituierter Hexaarylbenzole (HABs) mit ungewöhnlichen Symmetrien und mit bis zu fünf verschiedenen Substituenten zu realisieren. Dabei konnte jegliches Auftreten regioisomerer Produktverteilungen während der Reaktion ausgeschlossen werden. 4‐Nitroanilin wird dabei in...
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