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Electrode materials can have a significant impact on the course of an electrolysis reaction. Of particular interest is that different electrodes can generate different products from the same substrate. The electrode‐material‐selective transformations of styrene derivatives with molecular oxygen are reported. Platinum electrodes afford carbonyl products via cleavage of olefins, whereas tetrahydrofuran...
Die Wahl des Elektrodenmaterials bestimmt das Ergebnis bei elektrochemischen Reaktionen von Styrolen mit molekularem Sauerstoff. Wie K. Chiba und Mitarbeiter in ihrer Zuschrift auf S. 131 berichten, liefern Platinelektroden selektiv unter Doppelbindungsspaltung die Carbonylverbindungen (wie der Samurai mit dem Platin‐Schwert), während Kohlenstoffelektroden die Styrol‐Dimerisierung unter Bildung von...
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