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The highly strained, phenylene‐derived organic cages are typically regarded as very rigid entities, yet their deformation potential and supramolecular properties remain underexplored. Herein, we report a pliable conjugated phenylene nanocage by synergistically merging rigid and flexible building blocks. The anisotropic cage molecule contains branched phenylene chains capped by a calix[6]arene moiety,...
The highly strained, phenylene‐derived organic cages are typically regarded as very rigid entities, yet their deformation potential and supramolecular properties remain underexplored. Herein, we report a pliable conjugated phenylene nanocage by synergistically merging rigid and flexible building blocks. The anisotropic cage molecule contains branched phenylene chains capped by a calix[6]arene moiety,...
Nonlinear‐optical (NLO) crystals require birefringent phase matching (BPM), particularly in the solar‐blind ultraviolet (UV) (200–280 nm) and deep‐UV (100–200 nm) regions. Achieving BPM requires optimization of optical dispersion along with having large birefringence. This requirement is especially critical for structures with low optical anisotropy, including classical phosphate UV–NLO crystals like...