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Catalytic reaction was performed in the unregarded temperature region over silver catalysts with long catalytic lifetime for the conversion of methanol to methyl formate. Oα-saturated or Oγ-saturated silver catalysts were studied individually to identify the roles of Oα, Oγ in the oxidative esterification of methanol over an unsupported polycrystalline silver catalyst. A synergic process is proposed...
The partial oxidation of methane with molecular oxygen was performed on Fe–Mo/SiO2 catalysts. Iron was loaded on the Mo/SiO2 catalyst by chemical vapor deposition of Fe3(CO)12. The catalyst showed good low‐temperature activities at 723–823 K. Formaldehyde was a major condensable liquid product on the prepared catalyst. There were synergistic effects between iron and molybdenum in Fe–Mo/SiO2 catalysts...
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