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In photocatalytic anticorrosion perspective, the migration rate of excited electrons from surface layers to substrate steels restricted the performance of g‐C3N4 due to the high resistance between interface of g‐C3N4 layers and adhesive layers. Herein, an S‐scheme g‐C3N4/polyaniline (PANI) heterojunction with face‐to‐face structure was established by a secondary calcining method. The as‐prepared heterojunctions...