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Cationic doping is mainly used to improve the performance of rocksalt‐structured GeTe thermoelectric materials. However, its counterpart anionic doping is scarcely facilitated. Here, a comprehensive discussion is provided on doping at the anion site of rocksalt‐structured thermoelectric materials, surrounding its influence on bonding mechanisms, carrier and phonon transport characteristics, and thermoelectric...
Driven by the ability to harvest waste heat into reusable electricity and the exclusive role of serving as the power generator for deep spacecraft, intensive endeavors are dedicated to enhancing the thermoelectric performance of ecofriendly materials. Herein, the most recent progress in superhigh‐performance GeTe‐based thermoelectric materials is reviewed with a focus on the crystal structures, phase...
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