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Metal‐Organic Frameworks
In article number 2311140, Banglin Chen, Yuanbin Zhang, and co‐workers design a robust metal‐organic framework CuZrF6‐TPA with specific propyne trapping sites for efficient propyne/propadiene separation by simultaneously creating multiple propyne adsorption sites and multiple supramolecular interactions. This material enables both extremely high propyne uptake and benchmark...
Separating propyne/propadiene to produce pure propadiene is extremely challenging in industry due to their similar properties. Herein, a novel ZrF62− anion pillared cage‐like metal‐organic framework (termed as CuZrF6‐TPA) for highly efficient propyne/propadiene separation is reported. It exhibits high propyne capacity (177.4/188.6 cm3/cm3 at 0.5/1.0 bar and 298 K), benchmark separation selectivity...
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