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Photocatalytic Hydrogen Production
In article number 2207765, Megalamane Siddaramappa Bootharaju, Jong Suk Yoo, Nanfeng Zheng, Taeghwan Hyeon, and co‐workers show how gold doping selectively at the core of a 44‐atom silver nanocluster can modulate the electronic structure and enhance the stability of the resulting gold–silver core–shell sub‐nanostructure through synergistic effects. Increased interfacial...
While core–shell nanomaterials are highly desirable for realizing enhanced optical and catalytic properties, their synthesis with atomic‐level control is challenging. Here, the synthesis and crystal structure of [Au12Ag32(SePh)30]4−, the first example of selenolated Au–Ag core–shell nanoclusters, comprising a gold icosahedron core trapped in a silver dodecahedron, which is protected by an Ag12(SePh)...
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