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A 2D supramolecular organic framework (SOF) based on synthetic macrocycles has been constructed in water by a self‐assembly strategy. Two new organic monomers of this SOF, possessing viologen and azobenzene functional groups, form a stimuli‐responsive host–guest system upon cooperatively binding with cucurbit[8]uril rings. The reversible formation and dissociation of 2D SOF can be realized by the...
2D supramolecular organic frameworks (SOFs) with unique structural features have shown potential applications in chemistry and materials science. This article describes the construction of light/azoreductase‐responsive 2D SOFs through the assembly of cucurbit[8]urils, tetraphenylethene‐bridged viologen tetramers, and azobenzene dimers. This material is used as a fluorescence probe to detect azoreductase...
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