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This study reports the pyrolysis of the acid-impregnated cellulose at 50–325°C. The presence of acid is found to significantly change cellulose pyrolysis mechanism. While the pyrolysis of raw cellulose mainly proceeds with depolymerisation reactions, the pyrolysis of the acid-impregnated cellulose is dominantly contributed by dehydration reactions. The acid impregnation process seems to weaken the...
This study reports the effect of MgCl2 loading on the evolution of reaction intermediates during cellulose fast pyrolysis at 325°C. The loading of MgCl2 significantly changes the reaction pathways of cellulose pyrolysis and enhances the cross-linking of hydroxyl groups to release water even during the heating-up stage, as a result of the weakened hydrogen bonding networks during both the wet impregnation...
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